When Robinson Crusoe got to the island,the first thing he did was to look for some food.

A. who B. that C. which D. whom

B 【解析】 句意:當(dāng)魯濱遜·克魯索到達(dá)島上時(shí),他做的第一件事就是尋找一些食物。先行詞thing指物，而且被序數(shù)詞first修飾,故用that引導(dǎo)定語從句。故選B。
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